US restarts DUF6 conversion

28 October 2022


The US Department of Energy (DOE) Office of Environmental Management (EM) has restarted depleted uranium hexafluoride (DUF6) conversion at its improved Portsmouth and Paducah facilities. Both of EM’s conversion plants that recycle DUF6 to safer and more beneficial products are back in business with improved safety and sustainability measures following a COVID-19 operational pause, DOE noted.

“Conversion of DUF6 is now back online, with improved safety, performance and facilities thanks to deliberate conduct of operations and maintenance during the safety pause,” said Joel Bradburne, manager of EM’s Portsmouth/Paducah Project Office (PPPO), which oversees the project.

The Paducah facility in western Kentucky was the first to restart, in November 2021. EM’s conversion contractor then used the same gradual and rigorous process as Paducah to ensure a return to safe and deliberate operations at its Portsmouth Site in Ohio during the past several months.

Under pandemic protocols, EM took the opportunity to install and implement new equipment and processes to ensure improved safe production going forward. Significant among the improvements is a new “bulk hydrogen” backup system that ensures continuous, uninterrupted delivery of hydrogen to the conversion process in case of hydrogen-generation outages. The new system stores and delivers excess hydrogen produced from onsite generating units, and supports receipt of hydrogen delivered by truck. It was designed in collaboration with PPPO prime contractor, Mid-America Conversion Services, and subcontractor Air Products.

“This important infrastructure project has improved the stability of the conversion process and helped avoid operational upsets, reducing the need for intervention by plant personnel,” said Zak Lafontaine, PPPO’s DUF6 programme manager. “The bulk hydrogen upgrade has been instrumental in improving the versatility and reliability of operations at both plants. In less than a year, we can already directly attribute more than 50 days of additional conversion operations to this key plant improvement.”

EM’s conversion facilities, commissioned in 2010 and 2011, were specially designed and constructed to convert DUF6 at the former gaseous diffusion plants that enriched uranium for national security and commercial energy uses since the early 1950s. The result of conversion is a more stable uranium oxide along with aqueous hydrogen fluoride for disposition, storage and reuse. Approximately 740,000 metric tons of DUF6 remain to be converted over the next several decades.


Image: The US DOE Office of Environmental Management has restarted depleted uranium hexafluoride conversion at its Portsmouth and Paducah facilities (courtesy of US DOE EM)



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